Hm. Christen et al., SMALL-SIGNAL DIELECTRIC-RELAXATION IN THE DISORDERED PEROVSKITE PB(MG1 3NB2/3)O3/, Journal of physics. Condensed matter, 6(13), 1994, pp. 2631-2642
Decay-current and conventional dielectric measurements have been perfo
rmed on single-crystal samples of the disordered perovskite Pb(Mg1/3Nb
2/3)O3 (PMN). Low-frequency dielectric data of Colla and co-workers on
the same system are critically reanalysed and compared to our results
. In contrast to previously proposed spin-glass or master-plot approac
hes, we suggest a phenomenological description in terms of alpha- and
beta-relaxations: a relatively high-frequency beta-process takes over
when the characteristic alpha-relaxation time becomes extremely long.
The continuous slowing down of polar motion distinguishes PMN from rel
ated compounds such as Pb(Zn1/3Nb2/3)O3, for which, in contrast to PMN
, there is evidence of a structural phase transition.