H. Nankai et al., HYDROXYLATION OF 2 SATURATED ACYCLIC MONOTERPENOIDS, TETRAHYDROGERANIOL AND TETRAHYDROLAVANDULOL, BY THE PLANT-PATHOGENIC FUNGUS GLOMERELLA-CINGULATA, Journal of natural products, 60(3), 1997, pp. 287-289
The microbial transformations by Glomerella cingulata of two saturated
acyclic monoterpenoids, tetrahydrogeraniol (1) and tetrahydrolavandul
ol (3), were investigated. Both compounds were hydroxylated regioselec
tively at the isopropyl group. Tetrahydrogeraniol was transformed to h
ydroxycitronellol (2), while tetrahydrolavandulol was transformed to 5
-hydroxytetrahydrolavandulol (4). This is the first report describing
the microbial transformation of compounds 1 and 3.