Combustion of RDX was studied under self-deflagrating and CO, laser-as
sisted conditions at atmospheric pressure in air. Steady measurements
included near-surface temperature (embedded microthermocouple), melt l
ayer thickness, and sensitivity of burning rate to initial temperature
and radiant flux. Unsteady measurements of oscillatory burning rate w
ere also obtained using the laser-recoil technique. Thermocouple data
showed a relatively thick (several hundred mu m) melt layer, which inc
reased in thickness with increasing laser flux but remained at a relat
ively constant temperature of about 650 K. The temporally fluctuating,
spatially isothermal (time-averaged) nature of the melt layer suggest
that a bubbling/mixing mechanism plays an important transport role in
this zone. The temperature- and radiant flux-burning rate sensitivity
data show that the equivalence principle is reasonably accurate for R
DX under these conditions. The response function data agree qualitativ
ely with those of Finlinson, et nl. The classical, quasisteady ZN mode
l does not fit RDX combustion, at least at 1 arm, presumably due to co
nditions in the melt layer (e.g., bubble-induced mixing) which violate
model assumptions. Nevertheless these unsteady combustion data should
be useful for validating more comprehensive RDX combustion models.