The dissolution of pure plutonium metal reference material (99.977%) i
n a HNO3-HCOOH mixture is considerably enhanced by ultrasonic irradiat
ion with intensity 1 W/cm(2) and frequency 20 kHz under an argon atmos
phere. The tested medium is potentially suitable for preparing standar
d plutonium solution. At [HNO3] = 0.5-1.0 M and [HCOOH] = 1.0-2.0 M th
e rate of sonochemical dissolution is as much as 17 times higher than
that for the unsonicated process. The dissolution of plutonium metal w
ithout sonication leads to Pu(III) accumulation in solution. Under son
ication at [HNO3] greater than or equal to 1 M Pu(III) is oxidized to
Pu(IV) due to HNO2 accumulation as a result of HNO3 sonolysis. It is a
ssumed that ultrasound removes the passivating layer from the metal su
rface and accelerates of the mass-transfer processes near the extended
liquid-solid interface. The formation of CO2 under sonication of HNO3
-HCOOH mixtures shows that slow sonochemical denitration also occurs i
n the system investigated.