Xm. Zhang et al., BINARY-ALLOYS OF NYLON-1010 AND ETHYLENE-PROPYLENE COPOLYMER - CHEMICAL, MORPHOLOGICAL, AND MECHANICAL ANALYSIS, Polymer-plastics technology and engineering, 36(2), 1997, pp. 273-283
The modification of ethylene-propylene copolymer (EPM) has been accomp
lished by melt grafting of maleic anhydride (MAH) molecules promoted b
y radical initiators. The resulting EPM-g-MAH and EPM have been used t
o obtain binary nylon 1010/EPM or nylon 1010/EPM-g-MAH blends by melt
mixing. It was found that the EPM-g-MAH copolymer used as the second c
omponent has a profound effect upon the properties of the resulting bl
ends. This behavior has been attributed to a series of chemical and ph
ysicochemical interactions taking place between the two components. Th
e interactions are due to the presence of the anhydride functionality
on the copolymer and do not occur when this functionality is absent. T
he interaction has been confirmed by Fourier-transform infrared spectr
oscopy, differential scanning calorimetry, dynamic mechanical analysis
, and scanning electron microscopic.