Am. Rubio et Jj. Freire, TRICRITICAL BEHAVIOR OF AN OFF-LATTICE FLEXIBLE POLYMER MODEL - MONTE-CARLO CALCULATION OF 2ND VIRIAL-COEFFICIENTS, The Journal of chemical physics, 106(13), 1997, pp. 5638-5647
Simulation data of second virial coefficients have been obtained for a
n off-lattice model of linear polymer chains by means of Monte Carlo m
ethod with different values of the variable that describes intramolecu
lar attractions between units. The data have allowed us to study the t
heta, or tricritical, region where binary interactions cancel out. The
se Monte Carlo results are quantitatively compared with numerical pred
ictions from the tricritical renormalization group theory. With this p
urpose, we have employed the same values for the three-body and the cu
toff theoretical parameters that were previously used to reproduce the
mean size data. (C) 1997 American Institute of Physics.