H. Kasahara et al., ENANTIOSELECTIVE ACCUMULATION OF (-)-PINORESINOL THROUGH O-DEMETHYLATION OF (+ -)-EUDESMIN BY ASPERGILLUS-NIGER/, Phytochemistry, 44(8), 1997, pp. 1479-1482
Microbial transformation of (+/-)-eudesmin by Aspergillus niger was in
vestigated. Enantioselective accumulation of (-)-pinoresinol was shown
through O-demethylation of (+/-)-eudesmin. This fungus O-demethylated
both enantiomers of eudesmin, but the conversion rates for each enant
iomer were clearly different. Copyright (C) 1997 Elsevier Science Ltd.