TETRATHIAFULVALENES IN MACROCYCLIC AND SUPRAMOLECULAR CHEMISTRY

Authors
BECHER J LI ZT BLANCHARD P SVENSTRUP N LAU J NIELSEN MB LERICHE P
Citation
J. Becher et al., TETRATHIAFULVALENES IN MACROCYCLIC AND SUPRAMOLECULAR CHEMISTRY, Pure and applied chemistry, 69(3), 1997, pp. 465-470
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Pure and applied chemistry → ACNP
ISSN journal
00334545
Volume
69
Issue
3
Year of publication
1997
Pages
465 - 470
Database
ISI
SICI code
0033-4545(1997)69:3<465:TIMASC>2.0.ZU;2-1
Abstract
We describe that use of a stepvise selective protection-deprotection o f tetrathiafulvalene (TTF)-thiolates give rise to either two or three- dimensional macrobicyclic tetrathiafulvalenophanes in high yields by c onvergent syntheses. Configurationally selective self-assembly of cycl ic or bicyclic tetrathiafulvalenes using the cyclic pi-acceptor cyclo- bis(paraquat-p-phenylene) yields [2]- or [3]pseudocatenanes.