The investigation of MIS structures on silicon substrate grown by a mo
lecular layering (ML)-atomic layer epitaxy (ALE) method has been descr
ibed. Insulators consisting of an aluminum oxide matrix with 4 monolay
ers of heterooxides in their bulk were grown as a model of the charge
trapping centers. Electrical characteristics of these samples were mea
sured by a C-V technique. The value and the sign of the charge trappin
g centers were determined by growth conditions and post annealing. Kin
etics of charge trapping in the heterooxides showed a strong dependenc
e on the location of heterooxides in an aluminum oxide matrix. The lar
est value of a charge was obtained in the samples with heterooxides i
ntroduced to the matrix close to the silicon-insulator interface. As t
he intrinsic capture centers in aluminum oxide showed no traps at 77 K
, heterooxides actually captured the charge.