A series of sunlight-irradiated, smog-chamber experiments confirmed th
at the atmospheric organic aerosol formation potential of whole gasoli
ne vapor can be accounted for solely in terms of the aromatic fraction
of the fuel. The total amount of secondary organic aerosol produced f
rom the atmospheric oxidation of whole gasoline vapor can be represent
ed as the sum of the contributions of the individual aromatic molecula
r constituents of the fuel. The urban atmospheric, anthropogenic hydro
carbon profile is approximated well by evaporated whole gasoline, and
thus these results suggest that it is possible to model atmospheric se
condary organic aerosol formation.