SIMULTANEOUS COMPARISON OF DELTA-P-31 AND (1)J(PN) FOR THE ASSIGNMENTOF E Z-STEREOCHEMISTRY OF THE PHOSPHORUS-NITROGEN DOUBLE-BOND IN IMINOPHOSPHINES R-P=N-R'/

Authors
GUDAT D NIECKE E
Citation
D. Gudat et E. Niecke, SIMULTANEOUS COMPARISON OF DELTA-P-31 AND (1)J(PN) FOR THE ASSIGNMENTOF E Z-STEREOCHEMISTRY OF THE PHOSPHORUS-NITROGEN DOUBLE-BOND IN IMINOPHOSPHINES R-P=N-R'/, Fresenius' journal of analytical chemistry, 357(5), 1997, pp. 482-484
Citations number
9
Categorie Soggetti
Chemistry Analytical
Journal title
Fresenius' journal of analytical chemistry → ACNP
ISSN journal
09370633
Volume
357
Issue
5
Year of publication
1997
Pages
482 - 484
Database
ISI
SICI code
0937-0633(1997)357:5<482:SCODA(>2.0.ZU;2-V
Abstract
The analysis of P-31 and N-15 NMR data of a series of 40 iminophosphin es R-P = N-R' reveals that the E/Z-stereochemistry of the PN double bo nd can be predicted on the basis of a simultaneous comparison of the v alues of delta(31)p and (1)J(PN).