IR STUDY OF DISTRIBUTION OF PRIMARY AND SECONDARY FUNCTIONAL-GROUPS IN HIGHLY SUBSTITUTED CELLULOSE ACETATES, ACETOMALEATES, AND ACETOPHTHALATES

Authors
KRASOVSKII AN PLODISTYI AB POLYAKOV DN
Citation
An. Krasovskii et al., IR STUDY OF DISTRIBUTION OF PRIMARY AND SECONDARY FUNCTIONAL-GROUPS IN HIGHLY SUBSTITUTED CELLULOSE ACETATES, ACETOMALEATES, AND ACETOPHTHALATES, Russian journal of applied chemistry, 69(7), 1996, pp. 1048-1054
Citations number
19
Categorie Soggetti
Chemistry Applied
Journal title
Russian journal of applied chemistry → ACNP
ISSN journal
10704272
Volume
69
Issue
7
Year of publication
1996
Pages
1048 - 1054
Database
ISI
SICI code
1070-4272(1996)69:7<1048:ISODOP>2.0.ZU;2-0
Abstract
A study is made of the distribution of integral intensities of absorpt ion bands due to stretching vibrations of hydroxy groups at 3200-3700 cm(-1) and carbonyl groups at 1740-1750 cm(-1) in infrared spectra of highly substituted (c(a) = 60-61.5%) cellulose acetates, acetomaleates , and acetophthalates in methylene chloride solutions. The observed va riations in the distribution of the primary (C6) and secondary (C2 and C3) hydroxy (or carbonyl) groups are interpreted in terms of their re lative reactivity in the stages of cellulose activation and acetylatio n.