Citation
H. Kunkely et A. Vogler, PHOTOREACTIVITY OF COORDINATED PHENYLHYDRAZINE - INTRALIGAND EXCITATION OF RECL(CO)(3)(PHNH-NH2)(2), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 52(2), 1997, pp. 214-216
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
09320776
Volume
52
Issue
2
Year of publication
1997
Pages
214 - 216
Database
ISI
SICI code
0932-0776(1997)52:2<214:POCP-I>2.0.ZU;2-5
Abstract
The complex of ReCl(CO)(3)(PhNH-NH2)(2) shows an absorption band at la
mbda(max) = 272 nm which is assigned to an IL (intraligand) transition
of the coordinated phenylhydrazine. Upon IL excitation the complex un
dergoes a decomposition with phi = 0.03 at lambda(irr) = 280 nm.