C-13 EPR HYPERFINE INTERACTION IN THE COMPLEX [RH(CN)(6)](4-) IN A KCL HOST LATTICE

Authors
VUGMAN NV GIANNONI RA NETO JAC
Citation
Nv. Vugman et al., C-13 EPR HYPERFINE INTERACTION IN THE COMPLEX [RH(CN)(6)](4-) IN A KCL HOST LATTICE, Journal of magnetic resonance [1997], 124(2), 1997, pp. 352-354
Citations number
6
Categorie Soggetti
Physics, Atomic, Molecular & Chemical","Biochemical Research Methods
Journal title
Journal of magnetic resonance [1997] → ACNP
Volume
124
Issue
2
Year of publication
1997
Pages
352 - 354
Database
ISI
SICI code
Abstract
The hyperfine interaction with C-13 in nonenriched [Rh(CN)(6)](4-), in a KCl host lattice at 7 K, is measured by continuous-wave X- and Q-ba nd electron paramagnetic resonance, allowing, for the first time, a co mparative study of spin densities on the carbon of the axial cyanide i n this complex and in the similar [Co(CN)(6)](4-) complex. From the ex perimental data corrected for dipolar interactions, A(iso) = 79.80 x 1 0(-4) cm(-1) and A(anis) = 0.76 x 10(-4) cm(-1). (C) 1997 Academic Pre ss.