A novel RF pulse designed to perform adiabatic slice-selective excitat
ion for surface coils (ASSESS) is proposed in which Bo gradient is mod
ulated in concert with RF frequency modulation. Within the selected sl
ice, the principles of BIR4 pulses are employed to obtain well-defined
, pure-phase and self-refocused spin rotation of arbitrary flip angles
despite the presence of high B-1 inhomogeneity produced by surface co
ils. Outside the slice, advantage is taken of the B-1 field to dephase
equilibrium magnetization to achieve slice selection or outer-volume
suppression. This scheme should be useful for many localization techni
ques. Quaternion analysis of the overall propagator of the proposed pu
lse and numerical simulations using Bloch equations are performed. The
pulse is tested experimentally on a phantom sample. (C) 1997 Academic
Press.