THERMODYNAMICS OF A(1)C(60) (A=K, RB, CS) ALKALI FULLERIDES

Authors
GRANASY L PEKKER S FORRO L
Citation
L. Granasy et al., THERMODYNAMICS OF A(1)C(60) (A=K, RB, CS) ALKALI FULLERIDES, Fullerene science and technology, 5(2), 1997, pp. 325-342
Citations number
29
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical","Material Science
Journal title
Fullerene science and technology → ACNP
ISSN journal
1064122X
Volume
5
Issue
2
Year of publication
1997
Pages
325 - 342
Database
ISI
SICI code
1064-122X(1997)5:2<325:TOA(RC>2.0.ZU;2-T
Abstract
The thermodynamic properties of the A(1)C(60) (A=K, Rb, Cs) alkali ful lerides have been studied by conventional and modulated differential s canning calorimetry. The Gibbs free energies and the stability ranges of the monomer, dimer, and polymer phases are determined. The kinetics of phase transformation is investigated, and the mechanisms of polyme rization and phase separation are identified.