DEHYDRATION OF ALPHA-SILYLALCOHOLS IN THE REDUCTIVE CONVERSION OF ESTERS AND KETONES INTO ALKENES

Citation
A. Chenede et al., DEHYDRATION OF ALPHA-SILYLALCOHOLS IN THE REDUCTIVE CONVERSION OF ESTERS AND KETONES INTO ALKENES, Tetrahedron letters, 38(13), 1997, pp. 2381-2382
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
38
Issue
13
Year of publication
1997
Pages
2381 - 2382
Database
ISI
SICI code
0040-4039(1997)38:13<2381:DOAITR>2.0.ZU;2-L
Abstract
The conversion of esters and ketones into easily dehydrated a-silylate d alcohols, and protodesilylation of the resultant vinylsilanes, gives alkenes under relatively mild acidic conditions. (C) 1997 Elsevier Sc ience Ltd.