ARENEDIAZONIUM ION INSERTION INTO AN IRON PHOSPHINE BOND - SYNTHESIS AND CRYSTAL-STRUCTURE OF [FE(NO)2(PPH2CH2CH2P(PH)2NN(C6H4F-P))][PF6].OC4H8

Authors
ATKINSON FL CONNELLY NG CROSSLEY JG ORPEN AG
Citation
Fl. Atkinson et al., ARENEDIAZONIUM ION INSERTION INTO AN IRON PHOSPHINE BOND - SYNTHESIS AND CRYSTAL-STRUCTURE OF [FE(NO)2(PPH2CH2CH2P(PH)2NN(C6H4F-P))][PF6].OC4H8, Journal of the Chemical Society. Dalton transactions, (7), 1994, pp. 1161-1162
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
7
Year of publication
1994
Pages
1161 - 1162
Database
ISI
SICI code
0300-9246(1994):7<1161:AIIIAI>2.0.ZU;2-W
Abstract
The reaction of [Fe(NO)2(dppe)] (dppe = Ph2PCH2CH2PPh2) with [N2C6H4F- p][PF6] gave [Fe(NO)2{PPh2CH2CH2P(Ph)2NN(C6H4F-p)}][PF6] X-ray studies on which revealed the formation of a novel chelating ligand bound to iron through phosphine and eta2-N=N functionalities and resulting from insertion of an arenediazo group into an iron-phosphorus bond.