S. Olszewski et al., CORRELATION-EFFECTS IN A FEW-PARTICLE ONE-DIMENSIONAL COULOMB-INTERACTING SYSTEM, Theoretica Chimica Acta, 95(5-6), 1997, pp. 165-200
A model of the one-dimensional Coulomb-interacting few-particle system
is studied in detail. The model is similar to a many-electron system
which in a zero-order approximation of the non-interacting particles h
as only singly occupied one-electron levels. Such model cancels the di
vergencies in the Coulomb and exchange interaction energies found regu
larly for a conventional one-dimensional system which is built up of t
he doubly occupied one-electron levels and is submitted to the Coulomb
perturbation. In the present case, the correlated wave functions for
the system can be obtained from the Slater determinants constructed fo
r the sets of the one-electron levels and combined according to the ru
les given by the standard perturbation theory. The calculations allow
us to discuss the correlation influence and the effect of the size of
the model on: (i) the excitation energies including the criterion corr
esponding to the metal-insulator transition (the Mott transition), (ii
) the distribution of the correlated charge along the model, (iii) the
average velocity of a two-particle system being in different states,
and (iv) the dipole moments and transition probabilities. In the last
case, the lifetime of the uncorrelated and correlated excited states o
btained in the situation of the allowed one-photon transitions can be
compared with the lifetime obtained for a similar system in the case w
hen the one-photon transitions are forbidden and two-photon transition
s should be taken into account. No data other than the length of the m
odel and the fundamental constants of nature enter the calculations.