Jb. Laurens et Er. Rohwer, FACTORS INFLUENCING BREAKTHROUGH VOLUMES WHEN USING SORPTION TRAPS ATHIGH-FLOW RATES, HRC. Journal of high resolution chromatography, 20(2), 1997, pp. 119-121
The effects of the sample flow rate and bulk sample composition on the
breakthrough behaviour of H2S in small sorption traps were studied. T
he information is required for the optimization of high speed accumula
tion devices. At high flow rates the bulk thermal properties of the sa
mple affect the temperature inside the cooled traps and therefore also
the breakthrough volume. It was also found that the breakthrough volu
me, measured downstream of a packed trap, can actually increase with v
olume flow rate.