Ep. Turevskaya et al., BIMETALLIC ALKOXIDES OF BARIUM AND ZIRCONIUM - PREPARATION OF BAZRO3 POWDER, JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 8(1-3), 1997, pp. 111-115
Complex formation in solutions of barium and zirconium alkoxides in RO
H (R = i-Pr, Et) was studied. A number of bimetallic complexes were is
olated, and their structure and properties were studied. The sol-gel m
ethod yields a single-phase BaZrO3 powder only when i-PrOH solutions o
f the alkoxides are used. In this case, the oxocomplex, BaZrO(OPr-i)4
.(1-2)i-PrOH, is the precursor of the mixed oxide.