G. Mezinskis et al., MICROSTRUCTURES AND NANOSTRUCTURES OF FE2O3-SIO2 SOL-GEL DERIVED THICK COATINGS, JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 8(1-3), 1997, pp. 489-492
Thick Fe2O3SiO2 sol-gel coatings with 30 wt% Fe2O3 were prepared on gl
ass substrates under different conditions. These were investigated by
scanning electron and atomic force microscopies. The performance of th
e layers depended also on the way the substrate surface was pretreated
. Annealed bulk gel pieces showed phases like FeCl2 x 2H(2)O and presu
mably C9Fe2O9 (300 degrees C); at higher annealing temperatures, hemat
ite, cristobalite and magnetite could be found.