The Caribbean Sea is an area that traditionally has been considered ol
igotrophic, even though the Orinoco River contributes large quantities
of fresh water, nutrients, and other dissolved materials to this regi
on during the wet boreal (fall) season. Little is known about the impa
ct of this seasonal river plume, which extends from Venezuela to Puert
o Rico shortly after maximum discharge. Here we present results from a
study of the bio-optical characteristics of the Orinoco River plume d
uring the rainy season. The objective was to determine whether the coa
stal zone color scanner (CZCS) and the follow-on sea-viewing wide-fiel
d-of-view sensor (SeaWiFS) satellite instrument can be used to assess
the concentrations of substances in large river plumes. Recent in situ
shipboard measurements were compared to values from representative hi
storical CZCS images using established bio-optical models. Our goal wa
s to deconvolve the signatures of colored dissolved organic carbon and
phytoplankton pigments within satellite images of the Orinoco River p
lume. We conclude that the models may be used for case II waters and t
hat as much as 50% of the remotely sensed chlorophyll biomass within t
he plume is an artifact due to the presence of dissolved organic carbo
n. Dissolved organic carbon originates from a number of sources, inclu
ding decay of dead organisms, humic materials from the soil, and gelbs
toff.