H. Suematsu et al., THE ALPHA-BETA TRANSFORMATION IN SILICON-NITRIDE SINGLE-CRYSTALS, Journal of the American Ceramic Society, 80(3), 1997, pp. 615-620
Single crystals of alpha-Si3N4 were annealed at 2000 degrees-2150 degr
ees C. The beta phase was detected after annealing at 2150 degrees C o
nly when the crystals were surrounded by MgO . 3Al(2)O(3) or Y2O3 powd
ers. On the other hand, no evidence of the alpha-beta transformation w
as found when the crystals were annealed without additives. The soluti
on-precipitation mechanism was concluded to be the dominant factor in
the alpha-beta transformation of Si3N4.