C. Gahn et H. Mersmann, THEORETICAL PREDICTION AND EXPERIMENTAL-DETERMINATION OF ATTRITION RATES, Chemical engineering research & design, 75(A2), 1997, pp. 125-131
When reasonably soluble substances (c > 0.1 mol l(-1)) are crystalliz
ed at a high specific power input and within their metastable zone, at
trition is a primary source of nucleation. The study presented here is
an attempt to quantify this attrition mechanism. Firstly, a physical
model is introduced which relates the attrition resistance of a crysta
lline substance to its mechanical properties. In the second part, the
emphasis is placed on the determination of the relevant mechanical pro
perties, hardness, elastic constants, and fracture resistance. The phy
sical model will finally be compared to experimental results. A good a
greement is found between the experimentally determined and theoretica
lly predicted attrition behaviour.