PHOTOCHEMICAL-REARRANGEMENT OF 2-BROMOVINYL SELENIDES

Authors
MORLEY CP
Citation
Cp. Morley, PHOTOCHEMICAL-REARRANGEMENT OF 2-BROMOVINYL SELENIDES, Synthesis, (3), 1997, pp. 279
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
3
Year of publication
1997
Database
ISI
SICI code
0039-7881(1997):3<279:PO2S>2.0.ZU;2-1
Abstract
UV irradiation of 2-bromocyclohexenyl alkyl selenides leads to rearran gement via a 1,3-hydrogen shift, and exclusive formation of the 6-brom o derivative, as evidenced in particular by multinuclear NMR spectrosc opic data; analogous cyclooctenyl compounds do not undergo this proces s.