A NEW EFFICIENT SYNTHESIS OF 3-NITROPYRIDINE AND SUBSTITUTED DERIVATIVES

Authors
Citation
Jm. Bakke et E. Ranes, A NEW EFFICIENT SYNTHESIS OF 3-NITROPYRIDINE AND SUBSTITUTED DERIVATIVES, Synthesis, (3), 1997, pp. 281
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397881
Issue
3
Year of publication
1997
Database
ISI
SICI code
0039-7881(1997):3<281:ANESO3>2.0.ZU;2-G
Abstract
Pyridine and pyridine derivatives have been nitrated in the beta-posit ion by reaction with N2O5 or NO2 . BF4 in MeNO(2), THF or MeCN to form the N-nitropyridinium salt. This was then reacted with an aqueous sol ution of a nucleophile to give the beta-nitro compound in moderate to good yield.