AQUATION KINETICS OF CHLOROPENTAMMINECOBALT(III) PERCHLORATE IN DICARBOXYLATE MEDIA CONTAINING 10-PERCENT (V V) ACETONE/

Authors
ZAGHLOUL AA KHALIL MM AMIRA MF
Citation
Aa. Zaghloul et al., AQUATION KINETICS OF CHLOROPENTAMMINECOBALT(III) PERCHLORATE IN DICARBOXYLATE MEDIA CONTAINING 10-PERCENT (V V) ACETONE/, International journal of chemical kinetics, 29(4), 1997, pp. 311-316
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
International journal of chemical kinetics → ACNP
ISSN journal
05388066
Volume
29
Issue
4
Year of publication
1997
Pages
311 - 316
Database
ISI
SICI code
0538-8066(1997)29:4<311:AKOCPI>2.0.ZU;2-F
Abstract
The aquation kinetics of [Co(NH3)(5)Cl](2+) in dicarboxylate media con taining 10% (v/v) acetone is measured in the temperature range of 35-6 0 degrees C. A new empirical correlation between the rate coefficient, k(obs), and the stoichiometric concentration of the dicarboxylate lig and (C-L) has been established and a reaction mechanism is proposed. ( C) 1997 John Wiley & Sons, Inc.