The electrochemical characterization of aluminium anodes containing di
fferent intermetallic compounds in 3% sodium chloride and 0.3% sodium
sulphate aqueous solutions was carried out by means of d.c. measuremen
ts. The case of some Ca-Zn, Ca-In and Al-Mg-Zn intermetallic compounds
in the aluminium matrix was examined. SEM and EDAX analyses were used
to examine the surface structure of the anodic materials. The relatio
nship between morphological structure and electrochemical results was
studied and particular attention was paid to the influence of the inte
rmetallic phases on the activation of aluminium anode materials. Diffe
rent heat treatments, performed to ensure the dispersion of the fine i
ntermetallic phases, were adopted and the results are briefly discusse
d.