An. Papathanassiou et J. Grammatikakis, PRESSURE VARIATION OF THE ELECTRICAL-CONDUCTIVITY OF DOLOMITE [CAMG(CO3)(2)], Physical review. B, Condensed matter, 53(24), 1996, pp. 16247-16251
The conductivity of dolomite is a decreasing function of pressure, ind
icating that the dominant mechanism is ionic in alkaline earth carbona
tes. The activation volume upsilon(act) at room temperature is obtaine
d. The curvature observed in the logarithm of the conductivity versus
pressure plot is discussed in terms of the activation of multiple mech
anisms upon pressure or to the pressure dependence of upsilon(act). Th
e estimation of the migration volume upsilon(m) from ionic thermocurre
nt results through the cB Omega point defect parameter model yields to
the evaluation of the association volume upsilon(alpha).