SYNTHESIS OF AN IRON(II) COMPLEX VERSATILE FOR PREPARATION OF IRON(II) COMPLEXES WITH NOVEL PENTADENTATE LIGANDS VIA C-C BOND FORMATION WITH VARIOUS NITRILES - PROPANEDIYLIDENEIBIS(2-PYRIDYLMETHANAMINE)IRON(II) PERCHLORATE
M. Goto et al., SYNTHESIS OF AN IRON(II) COMPLEX VERSATILE FOR PREPARATION OF IRON(II) COMPLEXES WITH NOVEL PENTADENTATE LIGANDS VIA C-C BOND FORMATION WITH VARIOUS NITRILES - PROPANEDIYLIDENEIBIS(2-PYRIDYLMETHANAMINE)IRON(II) PERCHLORATE, Chemical communications, (6), 1997, pp. 539-540
A bis(acetonitrile)iron(II) complexes with thyl-1,3-propanediylidenebi
s(2-pyridyimethanamine) undergoes a nucleophilic addition to the nitri
le carbon on addition of triethylamine to a nitrile solution yielding
mono(acetonitrile)iron(II) complex with a novel pentadentate polyimine
ligand.