SYNTHESIS AND CHARACTERIZATION OF THE POTASSIUM 1,1-DITHIOLATE C12H20N2S2K2 - A NOVEL K12S12 CLUSTER COMPOUND

Citation
N. Kuhn et al., SYNTHESIS AND CHARACTERIZATION OF THE POTASSIUM 1,1-DITHIOLATE C12H20N2S2K2 - A NOVEL K12S12 CLUSTER COMPOUND, Chemical communications, (6), 1997, pp. 627-628
Citations number
21
Categorie Soggetti
Chemistry
Journal title
ISSN journal
13597345
Issue
6
Year of publication
1997
Pages
627 - 628
Database
ISI
SICI code
1359-7345(1997):6<627:SACOTP>2.0.ZU;2-N
Abstract
The carbene adduct 1 reacts with potassium to give the potassium 1,1-d ithiolate 2; its tetrahydrofuran adduct exhibits a cage structure cons isting of a hexagonal K6S6 prism incorporated into a twelve-membered K 6S6 ring connected both by direct K-S bonds and vinylidene type bridge s.