J. Hou et al., INVESTIGATIONS ON THE FIELD-INDUCED SWITCHING BEHAVIOR IN AN ANTIFERROELECTRIC LIQUID-CRYSTAL, Liquid crystals, 22(4), 1997, pp. 401-407
The switching currents and field-induced apparent tilt angles in an an
tiferroelectric liquid crystal, (R)-MHPOBC, were measured. The structu
ral differences among different smectic C subphases may sensitively r
eflect the field or temperature dependence of the apparent tilt angle.
In a thin cell, the apparent tilt angle was found to change in two st
eps as a function of field strength in the SmCalpha and SmC* phases:
a steep increase at lower fields and a small linear increase at higher
fields. The steep increase in apparent tilt angle is divided into two
parts via a plateau in the ferrielectric SmCgamma phase. Stepwise ch
ange with a plateau is also seen in the relation of apparent tilt angl
e versus temperature under various electric fields. Moreover, the appa
rent tilt angle in the vicinity of the plateau is almost temperature-
and field-independent, implying a preferred orientation of the molecul
es in the ferrielectric state. The influence of the cell thickness on
the structural changes was also investigated.