S. Jobic et al., STRUCTURAL DETERMINATION OF A NEW TERNARY CHROMIUM SULFIDE - CRSBS3, Comptes rendus de l'Academie des sciences. Serie 2, Mecanique, physique, chimie, sciences de l'univers, sciences de la terre, 318(7), 1994, pp. 893-900
CrSbS3 can be prepared by reaction of the elements in stoichiometric p
roportions at 1,030 K. This compound crystallizes in an orthorhombic s
ystem with the cell parameters a = 8,6652 (5) angstrom, b = 3.6188 (3)
angstrom, and c = 12.8720 (9) angstrom. The structural determination
was conducted on the P n m a space group with Z = 4 (R(F) = 3.7%, R(wF
) = 2.9%). The magnetic properties of the compound are discussed takin
g into account the geometric parameters.