E. Beniash et al., AMORPHOUS CALCIUM-CARBONATE TRANSFORMS INTO CALCITE DURING SEA-URCHINLARVAL SPICULE GROWTH, Proceedings - Royal Society. Biological Sciences, 264(1380), 1997, pp. 461-465
Sea urchin larvae form an endoskeleton composed of a pair of spicules.
For more than a century it has been stated that each spicule comprise
s a single crystal of the CaCO3 mineral, calcite. We show that an addi
tional mineral phase, amorphous calcium carbonate, is present in the s
ea urchin larval spicule, and that this inherently unstable mineral tr
ansforms into calcite with time. This observation significantly change
s our concepts of mineral formation in this well-studied organism.