STUDIES OF NICKEL(II) COMPLEXES OF 3-HYDROXYIMINOBUTANONE THIOSEMICARBAZONE AND 3-HYDROXYIMINOBUTANONE (4-PHENYL THIOSEMICARBAZONE) - CRYSTAL-STRUCTURE OF BIS(3-HYDROXYIMINOBUTANONE) (4-PHENYL THIOSEMICARBAZONE) NICKEL(II) NITRATE, MONOHYDRATE, [NI(C11H14N4OS)(2)](NO3)(2)CENTER-DOT-H2O

Authors
CHATTOPADHYAY SK CHATTOPADHYAY D BANERJEE T KURODA R GHOSH S
Citation
Sk. Chattopadhyay et al., STUDIES OF NICKEL(II) COMPLEXES OF 3-HYDROXYIMINOBUTANONE THIOSEMICARBAZONE AND 3-HYDROXYIMINOBUTANONE (4-PHENYL THIOSEMICARBAZONE) - CRYSTAL-STRUCTURE OF BIS(3-HYDROXYIMINOBUTANONE) (4-PHENYL THIOSEMICARBAZONE) NICKEL(II) NITRATE, MONOHYDRATE, [NI(C11H14N4OS)(2)](NO3)(2)CENTER-DOT-H2O, Polyhedron, 16(11), 1997, pp. 1925-1930
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
11
Year of publication
1997
Pages
1925 - 1930
Database
ISI
SICI code
0277-5387(1997)16:11<1925:SONCO3>2.0.ZU;2-R
Abstract
Nickel(II) complexes of two tridentate N.N.S-chelating ligands, 3-hydr oxyimino-butanonethiosemicarbazone (L(1)H(2)) and 3-hydroxyiminobutano ne (4-phenylthiosemicarbazone) (LH(2)), have been synthesized and char acterized by elemental analysis, IR, UV-vis spectroscopy and cyclic vo ltammetric studies. The structure of Ni(LH(2))(2)(NO3)(2) . H2O has be en determined by single-crystal X-ray diffraction. Nickel(II) is in a distorted octahedral N4S2 donor environment; one of the nitrate groups exhibits partial disorder. (C) 1997 Elsevier Science Ltd.