STUDY ON THE COORDINATION OF THE HYDROXYL GROUP - CRYSTAL-STRUCTURE AND FT-IR SPECTRA OF POTASSIUM HYDROGEN GALACTARATE

Authors
TIAN W LIAO H WU JG YANG GD
Citation
W. Tian et al., STUDY ON THE COORDINATION OF THE HYDROXYL GROUP - CRYSTAL-STRUCTURE AND FT-IR SPECTRA OF POTASSIUM HYDROGEN GALACTARATE, Polyhedron, 16(12), 1997, pp. 2055-2058
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
12
Year of publication
1997
Pages
2055 - 2058
Database
ISI
SICI code
0277-5387(1997)16:12<2055:SOTCOT>2.0.ZU;2-B
Abstract
Potassium hydrogen galactarate monohydrate was prepared for the first time. X-ray diffraction analysis showed that the K+ ion in this comple x is hepta-coordinated, and two of the four hydroxyl groups are coordi nated to the K+ ion. The complex forms a hydrogen bonding network. The results of the FT-IR spectra measurement an in agreement with the con clusion of X-ray crystal structural study. (C) 1997 Elsevier Science L td.