Carbon chains are of interest: in astrophysics and in terrestrial proc
esses, such as fullerene formation. The electronic spectra of a variet
y of such chains have now been identified in the laboratory using a te
chnique which enables absorption spectra of mass-selected species to b
e measured in neon matrices. The understanding of their transitions an
d the trends apparent for these homologous series point out which type
and size of carbon chains are relevant for consideration as carriers
of the diffuse interstellar bands.