T. Noma et al., STRUCTURAL STABILIZATION INDUCED BY OXYGEN PLASMA POSTEXPOSURE OF SIO2-FILMS DEPOSITED FROM TETRAETHOXYSILANE, Journal of physics. D, Applied physics, 30(6), 1997, pp. 937-943
Structural changes induced by post-exposure to oxygen plasma were stud
ied for SiO2 films deposited at low temperatures (200-600 degrees C) b
y plasma-enhanced chemical vapour deposition from tetraethoxysilane. C
arbon- and water-related impurities remaining in the film are decompos
ed by the oxygen plasma and then disappear. This brings about the disa
ppearance of micropores and structural consolidation and stabilization
, through which the degree of waterproofing improves, the relative die
lectric constant decreases and the absorption edge shifts towards a hi
gher energy.