O-O,O')(2,2'-BIPYRIDINE-N,N')(NITRATO-O)COPPER(II)

Citation
L. Zhang et al., O-O,O')(2,2'-BIPYRIDINE-N,N')(NITRATO-O)COPPER(II), Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 299-301
Citations number
7
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
3
Pages
299 - 301
Database
ISI
SICI code
0108-2701(1997)53:<299:O>2.0.ZU;2-F
Abstract
The Cu-II atom in the title complex, ato-O)(1-phenyl-1,3-butanedionato -O,O')copper(II), [Cu(C10H9O2)(NO3)(C10H8N2)], has a square-pyramidal coordination. Both the benzoylacetone anion and the 2,2'-bipyridine li gand chelate to the Cu-II atom in the equatorial plane, while a nitrat e anion occupies the apical site, with a longer Cu-O distance of 2.335 (4) Angstrom. Within the delocalized enol ring of benzoylacetone, the C-C bond closest to the phenyl ring is longer than the C-C bond farth est from the phenyl ring.