LEWIS BASE FUNCTIONALIZED CYCLOPENTADIENYL COMPLEXES OF TITANIUM

Authors
HUGHES AK MARSH SMB HOWARD JAK FORD PS
Citation
Ak. Hughes et al., LEWIS BASE FUNCTIONALIZED CYCLOPENTADIENYL COMPLEXES OF TITANIUM, Journal of organometallic chemistry, 528(1-2), 1997, pp. 195-198
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
528
Issue
1-2
Year of publication
1997
Pages
195 - 198
Database
ISI
SICI code
0022-328X(1997)528:1-2<195:LBFCCO>2.0.ZU;2-Q
Abstract
The reaction of Ti(NMe(2))(4) with the amine functionalised cyclopenta diene C5H5CH2CH2CH2N(H)CMe(3) gives the titanium cyclopentadienyl-amid e complex a(1)-(C(5)H(4)CH(2)CH(2)CH(2)NCMe(3))}(NMe(2))(2)] which rea cts with aniline to generate the phenylimido bridged dimer (5)-C5H4CH2 CH2CH2N(H)CMe(3))(NHPh))(2)(mu-NPh)(2)] whose molecular structure has been determined by X-ray diffraction, revealing a slightly asymmetric Ti(mu-NPh)(2)Ti core.