H D EXCHANGE-REACTIONS BETWEEN C6D6 AND C(5)ME(5)CO(CH2=CHR)(2) (R=H,SIME(3)) - EVIDENCE FOR OXIDATIVE ADDITION OF C-SP(2)-H BONDS TO THE [C(5)ME(5)(L)CO] MOIETY/

Authors
LENGES CP BROOKHART M GRANT BE
Citation
Cp. Lenges et al., H D EXCHANGE-REACTIONS BETWEEN C6D6 AND C(5)ME(5)CO(CH2=CHR)(2) (R=H,SIME(3)) - EVIDENCE FOR OXIDATIVE ADDITION OF C-SP(2)-H BONDS TO THE [C(5)ME(5)(L)CO] MOIETY/, Journal of organometallic chemistry, 528(1-2), 1997, pp. 199-203
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
528
Issue
1-2
Year of publication
1997
Pages
199 - 203
Database
ISI
SICI code
0022-328X(1997)528:1-2<199:HDEBCA>2.0.ZU;2-T
Abstract
Heating C(5)Me(5)Co(CH2=CHR), (R=H, 60 degrees C; R = SiMe(3), 20 degr ees C) in C6D6 leads to deuterium incorporation in the vinylic sites o f the olefin ligands. This observation is interpreted in terms of reve rsible oxidative addition of C6D6 to the 16-electron species [C(5)Me(5 )Co(CH2 = CHR)].