METALLACYCLES OF THE IMIDOYLAMIDINATO COMPOUNDS HNC(R)NC(R)NH AND GROUP-13 ELEMENTS - CRYSTAL-STRUCTURE OF THE COMPLEX [GAME(2)(HNC(CF3)NC(CF3)NH)]

Authors
ARIS DR BARKER J PHILLIPS PR ALCOCK NW WALLBRIDGE MGH
Citation
Dr. Aris et al., METALLACYCLES OF THE IMIDOYLAMIDINATO COMPOUNDS HNC(R)NC(R)NH AND GROUP-13 ELEMENTS - CRYSTAL-STRUCTURE OF THE COMPLEX [GAME(2)(HNC(CF3)NC(CF3)NH)], Journal of the Chemical Society. Dalton transactions, (6), 1997, pp. 909-910
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
6
Year of publication
1997
Pages
909 - 910
Database
ISI
SICI code
0300-9246(1997):6<909:MOTICH>2.0.ZU;2-K
Abstract
Reaction of trimethylgallium with trifluoroacetamidine [H2NC(CF3)NH] r esulted in an unusual elimination reaction, and yielded the air-stable volatile metallacycle [GaMe(2){HNC(CF3)NC(CF3)NH}] which shows a plan ar six-membered (GaNCNCN) ring; a related aluminium system. [AlMe(2){H NC(Ph)NC(Ph)NH}] was formed using benzamidine [H2NC(Ph)NH].