SYNTHESIS, CHARACTERIZATION AND CRYSTAL-STRUCTURES OF HETEROMETALLIC TRINUCLEAR CARBONYL SULFIDO CLUSTERS (ETA(5)-CP)MOFECO-(CO)(8)(MU(3)-S) AND [(ETA(5)-CP)MO](2)FE(CO)(7)(MU(3)-S)

Authors
XU F SUN WH YANG SY YIN YQ WU QJ YU KB
Citation
F. Xu et al., SYNTHESIS, CHARACTERIZATION AND CRYSTAL-STRUCTURES OF HETEROMETALLIC TRINUCLEAR CARBONYL SULFIDO CLUSTERS (ETA(5)-CP)MOFECO-(CO)(8)(MU(3)-S) AND [(ETA(5)-CP)MO](2)FE(CO)(7)(MU(3)-S), Transition metal chemistry, 22(2), 1997, pp. 176-179
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
22
Issue
2
Year of publication
1997
Pages
176 - 179
Database
ISI
SICI code
0340-4285(1997)22:2<176:SCACOH>2.0.ZU;2-O
Abstract
HFe2Co(CO)(9)(mu(3)-S) reacts with (eta(5)-Cp)Mo(CO)(3)Cl in refluxing THF to give heterometallic trinuclear clusters (eta(5)-Cp)MoFeCo(CO)( 8)(mu(3)-S) and [(eta(5)-Cp)Mo](2)Fe(CO)(7)(mu(3)-S), which have been characterized by elemental analyses, i.r., H-1- and C-13-n.m.r. and X- ray crystal structure determination. An electrophilic addition-elimina tion sequence is proposed for their formation.