P. Raback et al., THERMODYNAMIC CONSIDERATIONS OF THE ROLE OF HYDROGEN IN SUBLIMATION GROWTH OF SILICON-CARBIDE, Journal of the Electrochemical Society, 144(3), 1997, pp. 1024-1027
The purpose of this study was to investigate the thermodynamic consequ
ences of added hydrogen to the sublimation growth process of silicon c
arbide crystals. The results show that at each temperature there exist
s a level of hydrogen that leads to a silicon-to-carbon ratio of unity
. At typical growth temperatures the added hydrogen does not significa
ntly affect the supersaturation ratio.