K. Sugai et al., ALUMINUM METALLIZATION USING A COMBINATION OF CHEMICAL-VAPOR-DEPOSITION AND SPUTTERING, Journal of the Electrochemical Society, 144(3), 1997, pp. 1028-1035
An aluminum metallization process that combines blanket chemical vapor
deposition and sputtering was developed for use in fabrication of fut
ure ultralarge scale integration interconnections. Blanket chemical va
por deposition of aluminum using dimethylaluminum hydride on titanium
nitride, which provides superior step coverage and a smooth surface mo
rphology for films of less than approximately 0.15 mu m thickness, was
only used for hole-filling. Subsequent aluminum alloy sputtering, whi
ch has a high deposition rate and provides smooth surface films, was u
sed for the thickening of the aluminum films. This combination process
draws on the respective advantages of both chemical vapor deposition
and sputtering, which mutually compensate for each other's drawbacks.
As a result, via holes with a diameter of 0.3 mu m and an aspect ratio
of 2.7 were successfully filled. The resistance of contact holes fabr
icated by the combination process was slightly lower than that obtaine
d in the conventional tungsten plug process due to low film resistivit
y of chemically vapor deposited aluminum. The contact resistivity for
contacts to p- and n-type Si were 1.0 x 10(-7) and 2.9 x 10(-8) Omega
cm(2). respectively. Via hole resistance for 0.45 mu m diameter holes
was less than 1 Omega, which corresponds to a contact resistivity of l
ess than 1.6 x 10(-9) Omega cm(2) between chemically vapor deposited a
luminum and the underlayer titanium nitride.