A NEW SYNTHESIS OF TRANS-IODOHYDRINS USING IODINE-CERIUM(IV) SALTS

Authors
HORIUCHI CA IKEDA A KANAMORI M HOSOKAWA H SUGIYAMA T TAKAHASHI TT
Citation
Ca. Horiuchi et al., A NEW SYNTHESIS OF TRANS-IODOHYDRINS USING IODINE-CERIUM(IV) SALTS, Journal of chemical research. Synopses, (2), 1997, pp. 60-61
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
2
Year of publication
1997
Pages
60 - 61
Database
ISI
SICI code
0308-2342(1997):2<60:ANSOTU>2.0.ZU;2-X
Abstract
The reaction of cycloalkene with iodine-cerium(iv) ammonium nitrate (C AN) in acetonitrile-water (10:1-1:1) affords the corresponding trans-i odohydrins and trans-iodonitrates; when iodine-cerium(iv) sulfate (CS) in acetonitrile-water (10:1) at 50 degrees C is used, trans-iodohydri ns are obtained preferentially.