We have shown that the Fermi energy dependence on temperature in semim
etals keeps its well-known form, similar to that of semiconductors, do
wn to T = 0. In the nearest vicinity of T = 0 this dependence is signi
ficantly changed, and the Fermi level is displaced toward the top of t
he valence band. The more different electron and hole effective masses
in the model of the overlapped bands in semimetals are, the more suff
icient is this displacement. We note the specific role of substitution
al impurities in semimetals containing at least two atoms per elementa
ry cell. Of particular interest is the case when an impurity is of don
or type when it substitutes an atom in tile host elementary cell, and
of acceptor type when it substitutes another atom. This phenomenon can
be observed experimentally at low temperatures as oscillations of the
kinetic coefficients as functions of the impurity concentration, if t
he energies of the donor and acceptor levels are close to the Fermi en
ergy. We present selected experimental data obtained in Bi, which exhi
bit these oscillations.