THE VIBRATIONAL-SPECTRA AND THERMODYNAMIC PROPERTIES OF GASEOUS TETRAETHOXYTITANIUM, TI(OC2H5)(4)

Authors
VANDERVIS MGM KONINGS RJM OSKAM A
Citation
Mgm. Vandervis et al., THE VIBRATIONAL-SPECTRA AND THERMODYNAMIC PROPERTIES OF GASEOUS TETRAETHOXYTITANIUM, TI(OC2H5)(4), Vibrational spectroscopy, 14(1), 1997, pp. 87-93
Citations number
29
Categorie Soggetti
Spectroscopy,"Chemistry Analytical","Chemistry Physical
Journal title
Vibrational spectroscopy → ACNP
ISSN journal
09242031
Volume
14
Issue
1
Year of publication
1997
Pages
87 - 93
Database
ISI
SICI code
0924-2031(1997)14:1<87:TVATPO>2.0.ZU;2-Y
Abstract
The IR and Raman spectra of gaseous and liquid tetraethoxytitanium, Ti (OC2H5)(4), have been recorded and an assignment has been made. Compar ison of the spectra clearly shows the polymeric nature of tetraethoxyt itanium in the Liquid phase and monomeric molecules in the gas phase. In addition the thermodynamic properties of gaseous tetraethoxytitaniu m have been calculated using the present vibrational assignment and ad ditional information from the literature.