Dm. Kim et Eb. Nauman, NONTERMINATING POLYMERIZATIONS IN CONTINUOUS-FLOW SYSTEMS, Industrial & engineering chemistry research, 36(4), 1997, pp. 1088-1094
The feasibility or manufacturing narrow polydispersity polymers in con
tinuous flow systems is explored. The method of moments is applied to
ideal and more realistic kinetic schemes in a variety of reactor types
. In most cases, polydispersities approaching those;obtained in batch
can also be achieved in continuous reactors, but the long-term stabili
ty of a tubular reactor with species-dependent, radial diffusion remai
ns in doubt.